Methane Gas Hydrate Formation by Using Sodium Dodecyl Sulfate Additives
Keywords:
Hydrate, Gas hydrate, hydrate additives, Guest Gas CH4, seawater desalinationAbstract
Gas Hydrates (G. Hyd) such as methane (CH4) hydrates are forming of water molecules in ice-like crystals (lattice shape) with cavities where the methane gas (gust gas) molecules are engaged in, and this process is conducted in a certain condition, mainly in low temperature and high pressure. The objective of the current work is to study the effect of Sodium Dodecyl Sulfate (SDS) additives on Methane gas hydrate performance. Two solutions were prepared. The first solution consists of distilled water (100 ml), methane gas and SDS additives (0.10 g). The second solution consists of same ingredient with seawater (100 ml) instead of distilled water. A stirred tank with 750 psi has been utilized. The highest recovery ratio was 42.15% for distilled water using SDS additives with a pressure cycle duration of 120 minutes. Significant improvement in the hydrate water recovery ratio can be obtained with distilled water and seawater by about 42 % and 15.6% respectively. Generally, SDS additives improve the recovery rate for water in the presence of methane.
References
. U. Caldera, D. Bogdanov, S. Afanasyeva, C. Breyer, Role of Seawater Desalination in the Management of an Integrated Water and 100% Renewable Energy Based Power Sector in Saudi Arabia, Water. 10 (2017) 3, https://doi.org/10.3390/ w10010003.
. Bartolomé Ortega-Delgado, Matteo Cornali, Patricia Palenzuela, Diego C. Alarcón-Padilla. Operational analysis of the coupling between a multi-effect distillation unit with thermal vapor compression and a Rankine cycle power block using variable nozzle thermocompressors. Applied Energy 204 (2017) 690–701.
. Chong Wei Ong, Cheng-Liang Chen. Technical and economic evaluation of seawater freezing desalination using liquefied natural gas. Energy 181 (2019) 429-439.
. Syed M. Zubair, Mohamed A. Antar, Samih M. Elmutasim, Dahiru U. Lawal. Performance evaluation of humidification-dehumidification (HDH) desalination systems with and without heat recovery options: An experimental and theoretical investigation. Desalination 436 (2018) 161–175.
. Abhishek Nambiar, Ponnivalavan Babu, Praveen Linga. Improved Kinetics and Water Recovery with Propane as Co-Guest Gas on the Hydrate-Based Desalination (HyDesal) Process. ChemEngineering 2019, 3, 31; doi:10.3390/chem engineering 3010031.
. Veluswamy HP, Kumar S, Kumar R, Rangsunvigit P, Linga P. Enhanced clathrate hydrate formation kinetics at near ambient temperatures and moderate pressures: application to natural gas storage. Fuel 2016;182:907–19.
. T.J. Itsuno, K.H. Amabe, Vacuum distillation system aiming to use solar-heat for desalination, J. Arid L. Stud. 155 (2012) 153–155.
. Mekala P, Babu P, Sangwai JS, Linga P. Formation and dissociation kinetics of methane hydrates in seawater and silica sand. Energy Fuels 2014;28:2708–16.
. Sloan Jr. ED. Fundamental principles and applications of natural gas hydrates. Nature 2003;426:353.
. Ganji, H., Manteghian, M., Sadaghiani Zadeh, K., Omidkhah, M.R., Rahimi Mofrad, H., 2007. Effect of different surfactants on methane hydrate formation rate, stability and storage capacity. Fuel 86, 434–441.
. Okutani, K., Kuwabara, Y., Mori, Y.H., 2008. Surfactant effects on hydrate formation in an unstirred gas/liquid system: an experimental study using methane and sodium alkyl sulfates. Chem. Eng. Sci. 63, 183–194.
. Lin, W., Chen, G.J., Sun, C.Y., Guo, X.Q., Wu, Z.K., Liang, M.Y., Chen, L.T., Yang, L.Y., 2004. Effect of surfactant on the formation and dissociation kinetic behavior of methane hydrate. Chem. Eng. Sci. 59, 4449–4455.
. Zhang, J.S., Lee, S., Lee, J.W., 2007. Does SDS micellize under methane hydrate-forming conditions below the normal Krafft point? J. Colloid Interface Sci. 315, 313–318.
. Liu, Y., Chen, B., Chen, Y., Zhang, S., Guo, W., Cai, Y., Tan, B., Wang, W., 2015. Methane storage in a hydrated form as promoted by leucines for possible application to natural gas transportation and storage. Energy Technol. 3, 815–819.
. Bhattacharjee, G., Choudhary, N., Kumar, A., Chakrabarty, S., Kumar, R., 2016. Effect of the amino acid l-histidine on methane hydrate growth kinetics. J. Nat. Gas Sci. Eng. 35, 1453–1462.
. Veluswamy, H.P., Lee, P.Y., Premasinghe, K., Linga, P., 2017. Effect of biofriendly amino acids on the kinetics of methane hydrate formation and dissociation. Ind. Eng. Chem. Res. 56, 6145–6154.
. Babu, K., Maurya, N., Mandal, A., Saxena, V., 2015. Synthesis and characterization of sodium methyl ester sulfonate for chemically-enhanced oil recovery. Braz. J. Chem. Eng. 32, 795–803.
. Kumar, S., Kumar, A., Mandal, A., 2017. Characterizations of surfactant synthesized from Jatropha oil and its application in enhanced oil recovery. AIChE J. 63, 2731–2741.
. Rogers, R.E., Kothapalli, C., Lee, M.S., Woolsey, J.R., 2003. Catalysis of gas hydrates by biosurfactants in seawater-saturated sand/clay. Can. J. Chem. Eng. 81, 973–980.
. Chaturvedi, E., Prasad, N., Mandal, A., 2018. Enhanced formation of methane hydrate using a novel synthesized anionic surfactant for application in storage and transportation of natural gas. J. Nat. Gas Sci. Eng. 56, 246–257.
. Tobori, N., Kakui, T., 2019. Chapter 9 - methyl ester sulfonate. In: Hayes, D.G., Solaiman, D.K.Y., Ashby, R.D. (Eds.), Biobased Surfactants, second ed. AOCS Press, pp. 303–324.
. Linga, P.,Daraboina,N.,Ripmeester,J.A.,Englezos,P.,2012.Enhancedrateofgas hydrate formation in a fixed bed column filled with sand compared to a stirred vessel. Chem.Eng.Sci.68,617–623.
. Babu Pa., RajnishKumar, PraveenLinga Unusual behavior of propane as a co-guest during hydrate formation in silica sand: Potential application to seawater desalination and carbon dioxide capture /ChemicalEngineeringScience117(2014)342–351.
. R. De Deugd, M. Jager, J. de Swaan Arons, Mixed hydrates of methane and water-soluble hydrocarbons modeling of empirical results, AIChE J. 47 (2001) 693–704.
. Babu, P., Kumar R., Linga, P. ,2013. Medium pressure hydrate based gas separation (HBGS) process for pre-combustion capture of carbon dioxide employing a novel fixedbedreactor.Int.J.Greenh.GasControl17,206–214.
. Veluswamy HP, Kumar S, Kumar R, Rangsunvigit P, Linga P. Enhanced clathrate hydrate formation kinetics at near ambient temperatures and moderate pressures: application to natural gas storage. Fuel 2016;182:907–19.
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